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When I started in this field more than 12 years ago, combustion CFD simulations were typically done using CPU inexpensive approaches such as eddy break-up or flamelet combustion models with RANS. The use of complex chemistry in CFD, while offering a route to increased simulation realism, was very uncommon and considered impractical due to high CPU cost, and LES combustion was rarely applied for industrial applications.A lot has happened since then. LES calculations of events such as ignition and relight are becoming affordable, and while flamelet combustion models still are the best choice for many simulations (due to the excellent trade-off between CPU time and accuracy) using complex chemistry even on large meshes is common practice today.
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